You need to use a computer and click on "Withdrawal" and choose between "bank accounts, neteller, skrill, mastercard". I don't know if it can be done with the app, because I never used the app to make a withdrawl.
You also can order a debit card...
I have transfer money to my bank account and I have used Payoneer debit card and everything was ok.
The customer service is the worst I have ever seen and you need to lose a lot of time to talk with one of them and to have a solution.
You don't need a permanet stay permit or anagrafe registration. The one year rental agreement is enough.
You can start with Chebanca, BNL or Unicredit.